The slow component of the photoconductivity signal with a strong depen
dence of the relaxation time on the temperature, the photon energy, an
d the excitation intensity has been observed in the epitaxial layers o
f n- and p-type PbSe/BaF2 of thickness in the range 0.5-2 mu m. When t
he photon energy is more than twice as large as the band gap, the phot
oresponse signal reverses sign and the lifetime of the carriers increa
ses. The effect can be explained in terms of the capture of nonequilib
rium carriers, which account for the pinning of the Fermi level at the
semiconductor surface, into the surface states with a density on the
order of 10(13) cm(-2). The effect can also be explained in terms of t
he spatial separation of the carriers in the region of band bending ne
ar the surface. (C) 1996 American Institute of Physics.