M-XYLENE ISOMERIZATION OVER FE-SUBSTITUTED HZSM ZEOLITE - KINETIC ANDDEACTIVATION STUDIES

Authors
BOZGA G SANDULESCU I LINTES G LACATUS M
Citation
G. Bozga et al., M-XYLENE ISOMERIZATION OVER FE-SUBSTITUTED HZSM ZEOLITE - KINETIC ANDDEACTIVATION STUDIES, Revue Roumaine de Chimie, 40(11-12), 1995, pp. 1201-1212
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
40
Issue
11-12
Year of publication
1995
Pages
1201 - 1212
Database
ISI
SICI code
0035-3930(1995)40:11-12<1201:MIOFHZ>2.0.ZU;2-K
Abstract
m-Xylene gaseous phase isomerization over Fe-substituted HZSM zeolite catalyst was studied in a fixed bed continuous laboratory scale reacto r. To investigate the mechanism of transformations laking place on the inner surface of the catalyst, several experiments were carried. out in the presence of pyridine. The isomerization kinetics, including the catalyst deactivation by coke deposition were experimentally and theo retically examined, A kinetic model is formulated and its parameters e stimated for isothermal conditions at 673 K.