MOLECULAR DESIGN OF CATALYSTS ON THE BASIS OF FUNCTIONALIZED POLY(ETHYLENE OXIDE) AND BLOCK-COPOLYMERS OF ETHYLENE-OXIDE AND PROPYLENE-OXIDE

Citation
Ea. Karakhanov et al., MOLECULAR DESIGN OF CATALYSTS ON THE BASIS OF FUNCTIONALIZED POLY(ETHYLENE OXIDE) AND BLOCK-COPOLYMERS OF ETHYLENE-OXIDE AND PROPYLENE-OXIDE, Macromolecular symposia, 105, 1996, pp. 67-74
Citations number
12
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
10221360
Volume
105
Year of publication
1996
Pages
67 - 74
Database
ISI
SICI code
1022-1360(1996)105:<67:MDOCOT>2.0.ZU;2-Q
Abstract
Transition metal complexes based oil polyethylene oxide and copolymers of ethylene oxide and propylene oxide functionalized by dipyridyl, ac etylactone and catechol have been prepared, Macrocomplexes showed high activity and selectivity as catalysts in oxidation of cyclohexane, hy droxylation of benzene, epoxidation of hexene and allylic alcohol boun d by hydrogen peroxide, oxidation of ethylbenzene by dioxygen.