SPECTROSCOPIC STUDIES OF LEWIS-ACID BASE COMPLEXES .7. VIBRATIONAL-SPECTRA AND NORMAL-COORDINATE CALCULATIONS FOR TRIMETHYLPHOSPHINE-GALLIUM HALIDE-COMPLEXES
Rc. Taylor et Dlw. Kwoh, SPECTROSCOPIC STUDIES OF LEWIS-ACID BASE COMPLEXES .7. VIBRATIONAL-SPECTRA AND NORMAL-COORDINATE CALCULATIONS FOR TRIMETHYLPHOSPHINE-GALLIUM HALIDE-COMPLEXES, SPECT ACT A, 52(3), 1996, pp. 305-314
Raman and infrared spectra of normal and deuterated species of trimeth
ylphosphine-gallium tribromide and trimethylphosphine-gallium triiodid
e complexes have been obtained from microcrystalline solids, mulls and
KBr discs. Assignments are made and confirmed by normal coordinate an
alyses. For completeness, the calculations are extended to include min
or revisions to the results from the chloride complex previously publi
shed.