MOLECULAR-MASS CONTROL IN CIS-POLYPENTENY LENE SYNTHESIS CATALYZED WITH WCL6-DIMETHYLDIALLYLSILANE-EPICLOROHYDRIN

Citation
Va. Efimov et al., MOLECULAR-MASS CONTROL IN CIS-POLYPENTENY LENE SYNTHESIS CATALYZED WITH WCL6-DIMETHYLDIALLYLSILANE-EPICLOROHYDRIN, Vysokomolekularnye soedinenia. Seria A, 38(3), 1996, pp. 473-477
Citations number
16
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
38
Issue
3
Year of publication
1996
Pages
473 - 477
Database
ISI
SICI code
0507-5475(1996)38:3<473:MCICLS>2.0.ZU;2-Y
Abstract
Influence of the WCl6-dimethyldiallylsilane-epicolorhydrin catalyst co mposition and reaction conditions on the molecular mass distribution o f cis-polypentenylene was studied. The molecular mass of cis-polypente riylene was Shown to be controlled exclusively by chain transfer to di methyldiallylsilane.