CYCLOTRIMERIZATION OF ISOCYANATES IN THE PRESENCE OF ORGANOMETALLIC CATALYSTS - THE INTERACTION OF ISOCYANATES WITH HEXA-N-BUTYLDISTANNUM OXIDE

Authors
BADAMSHINA ER LODYGINA VP GRIGOREVA VA KOMRATOVA VV CHERVONNYI AD BATURIN SM
Citation
Er. Badamshina et al., CYCLOTRIMERIZATION OF ISOCYANATES IN THE PRESENCE OF ORGANOMETALLIC CATALYSTS - THE INTERACTION OF ISOCYANATES WITH HEXA-N-BUTYLDISTANNUM OXIDE, Vysokomolekularnye soedinenia. Seria A, 38(3), 1996, pp. 498-502
Citations number
14
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
38
Issue
3
Year of publication
1996
Pages
498 - 502
Database
ISI
SICI code
0507-5475(1996)38:3<498:COIITP>2.0.ZU;2-H
Abstract
Reaction of a number of isocyanates with hexa-n-butyldistannum oxide ( for the reactants taken in equimolar ratio) was investigated. Tin carb amates, existing as associates, were shown to be the products of this interaction. The catalytic activity of hexabutyldistannum oxide carbon ate, carbamate, and its hydrolysis products were studied in the cyclot rimerization of isocyanates. The carbamate and the products of its int eraction with isocyanate were shown to be responsible for the catalysi s of trimerization in the presence of hexa-n-butyldistannum oxide.