Oxygen gas was bombarded by ions of H-3(+) with an energy of 1 MeV, an
d the emission spectrum recorded in the wavelength range 320-950 nm. N
umerous spectral features from excited states in O, O+ and O-2(+) were
observed. The emission lines from the atomic ions (but not from neutr
al atoms) were found to be Doppler broadened, indicating that these ex
cited ions result from the energetic fragmentation of molecules. The l
ight emission of principal spectral features has been studied as a fun
ction of gas pressure, and the observations elucidate the different co
ntributions of projectile ions and electrons to the excitation process
. Such pressure curves may also be useful for line classification.