HIGH-YIELD AND FACILE CLUSTER REARRANGEMENTS IN THE 11-VERTEX NIDO SERIES OF TRICARBOLLIDES - NEW PARENT TRICARBABORANES [NIDO-7,8,10-C3B8H11](-) AND ARACHNO-5,6,9-C3B7H13

Authors
STIBR B HOLUB J CISAROVA I TEIXIDOR F VINAS C
Citation
B. Stibr et al., HIGH-YIELD AND FACILE CLUSTER REARRANGEMENTS IN THE 11-VERTEX NIDO SERIES OF TRICARBOLLIDES - NEW PARENT TRICARBABORANES [NIDO-7,8,10-C3B8H11](-) AND ARACHNO-5,6,9-C3B7H13, Inorganica Chimica Acta, 245(2), 1996, pp. 129-131
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
245
Issue
2
Year of publication
1996
Pages
129 - 131
Database
ISI
SICI code
0020-1693(1996)245:2<129:HAFCRI>2.0.ZU;2-M
Abstract
Thermal rearrangement of the zwitterionic 7-(Me(3)N)-nido-7,8,9-C3B8H1 0 (1a) and of the [nido-7,8,9-C3B8H11](-) anion (2) at 350 degrees C g ave high yields of the isomeric tricarbollide species 10-(Me(3)N)-nido -7,8,10-C3B8H10 (3a) and [nido-7,8,10-C3B8H10](-) (4), respectively, a nd oxidative degradation of one boron vertex in 4 resulted in the isol ation of the first parent ten-vertex tricarbaborane arachno-5,6,9-C3B7 H13 (5).