In the diffusion creep regime which is believed to be appropriate for
the lower mantle of the Earth, the viscosity of rocks depends on the g
rain size. The grain size is normally assumed to be constant in mantle
convection models. However, it is controlled by the kinetics of polym
orphic phase transformations and post-transformation grain growth and
can vary substantially. A simple scaling analysis demonstrates one par
ticular feature of the interaction of rheology, convection and kinetic
s: the mantle resembles a temperature-dependent viscosity fluid with a
n extremely unusual apparent activation enthalpy for the viscosity. It
can take almost any value including negative so that hotter regions c
an have a larger viscosity or the averaged viscosity of the mantle can
increase during Earth's secular cooling. This affects mantle dynamics
and evolution and should also be taken into account in interpretating
the viscosity variations in the mantle.