MASS AND MICROWAVE SPECTROSCOPIC STUDIES OF THE PYROLYSIS OF OXIME COMPOUNDS .2.

Citation
T. Sakaizumi et al., MASS AND MICROWAVE SPECTROSCOPIC STUDIES OF THE PYROLYSIS OF OXIME COMPOUNDS .2., Journal of analytical and applied pyrolysis, 36(1), 1996, pp. 99-102
Citations number
7
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
ISSN journal
01652370
Volume
36
Issue
1
Year of publication
1996
Pages
99 - 102
Database
ISI
SICI code
0165-2370(1996)36:1<99:MAMSSO>2.0.ZU;2-S
Abstract
The pyrolysates of three oximes (XCH(2)C(CH3)=NOH, X = H, CH3, Cl) hav e been investigated by pyrolysis-mass spectrometry/microwave spectrosc opy (Py-MS/MW). The pyrolysis mechanisms of XCH(2)C(CH3)=NOH (X = H an d CH3) were different from those of XCH(2)CH=NOH reported previously. Although the observed pyrolysates were different for the different sub stituent groups (X), acetonitrile was observed from all the precursors .