ACARBONYLBIS(TRICYCLOHEXYLPHOSPHINE)MOLYBDENUM(0), TRANS-[MO(CO)(4)(PCY(3))(2)]

Authors
ALYEA EC FERGUSON G KANNAN S
Citation
Ec. Alyea et al., ACARBONYLBIS(TRICYCLOHEXYLPHOSPHINE)MOLYBDENUM(0), TRANS-[MO(CO)(4)(PCY(3))(2)], Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 765-767
Citations number
24
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
4
Pages
765 - 767
Database
ISI
SICI code
0108-2701(1996)52:<765:AT>2.0.ZU;2-W
Abstract
The title compound, [Mo(CO)(4){P(C6H11)(3)}(2)], has crystallographic inversion symmetry and principal dimensions Mo-P 2.5436(9), Mo-C 2.020 (4) and 2.028 (3) Angstrom. The mean cone angle for the cyclohexyl-pho sphine ligand is 155 degrees, compared with 146 degrees for the cis is omer.