TRANS-[MO(CO)(4)(P(OME)(3))(2)]

Authors
CHAMPNESS NR HOPKINS AM REID G
Citation
Nr. Champness et al., TRANS-[MO(CO)(4)(P(OME)(3))(2)], Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 797-799
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
4
Pages
797 - 799
Database
ISI
SICI code
0108-2701(1996)52:<797:T>2.0.ZU;2-W
Abstract
Crystals of trans-tetracarbonylbis(trimethyl phosphite)molybdenum(0) c ontain discrete [Mo(C3H9O3P)(2)(CO)(4)] molecules whose metal atoms oc cupy crystallographic inversion centres. Valency angles at the Mo atom deviate from ideal octahedral values by no more than 3.3 (1)degrees. Mo-ligand bond lengths are normal, with an Mo-P distance of 2.4256 (8) and Mo-C distances of 2.041 (3) and 2.037 (4) Angstrom.