DIMERIC IODO[1,1-DI(2-PYRIDYL)-3-BUTENOLATO]COPPER(II) BIS(ACETONITRILE) SOLVATE, [CU2(C14H13N2O)(2)I-2]CENTER-DOT-2CH(3)CN

Authors
BHADURI S RUGMINI V SAPRE NY JONES PG
Citation
S. Bhaduri et al., DIMERIC IODO[1,1-DI(2-PYRIDYL)-3-BUTENOLATO]COPPER(II) BIS(ACETONITRILE) SOLVATE, [CU2(C14H13N2O)(2)I-2]CENTER-DOT-2CH(3)CN, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 804-806
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
4
Pages
804 - 806
Database
ISI
SICI code
0108-2701(1996)52:<804:DIB>2.0.ZU;2-7
Abstract
The title compound, pyridyl)-3-butenolato-N,O:N',O]bis[iodocopper(II)] bis(acetonitrile) solvate, was obtained from copper(I) iodide and the neutral ligand on reaction with oxygen. The olefinic function is unaf fected by the oxidation. The coordination at each Cu atom is trigonal bipyramidal and the coordination polyhedra share a common edge, which is the O ... O diagonal of the central Cu2O2 ring.