)(4)(PME(3))(4)(MU-H)(MU-SICL2)][FE(CO)(4)(SICL3)]

Authors
SIMONS RS TESSIER CA
Citation
Rs. Simons et Ca. Tessier, )(4)(PME(3))(4)(MU-H)(MU-SICL2)][FE(CO)(4)(SICL3)], Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 840-842
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
4
Pages
840 - 842
Database
ISI
SICI code
0108-2701(1996)52:<840:)>2.0.ZU;2-Y
Abstract
The structure of -mu-hydrido-tetrakis(trimethylphosphine)diiron(1+) te tracarbonyl(trichlorosilyl)ferrate(1-), has been determined at 119 K. The cation has an Fe-Fe distance of 2.947 (2) Angstrom and an average Fe-Si distance of 2.249 (3) Angstrom. A bridging hydride was located f rom a difference map with Fe-H distances of 1.77 and 1.63 Angstrom. Th e anion has an Fe-Si distance of 2.238 (3) Angstrom.