LOW-TEMPERATURE STRUCTURES OF HYDROFURAN)(D,L-TETRAHYDROFURFURANOL)TITANIUM(III) AND HYDROFURAN)(D,L-TETRAHYDROFURFUROXIDE)TITANIUM(IV)

Authors
OLEJNIK Z LIS T UTKO J SOBOTA P
Citation
Z. Olejnik et al., LOW-TEMPERATURE STRUCTURES OF HYDROFURAN)(D,L-TETRAHYDROFURFURANOL)TITANIUM(III) AND HYDROFURAN)(D,L-TETRAHYDROFURFUROXIDE)TITANIUM(IV), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 847-850
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
4
Pages
847 - 850
Database
ISI
SICI code
0108-2701(1996)52:<847:LSOH>2.0.ZU;2-Q
Abstract
The title compounds, (I) [TiCl3(C5H10O2)(C4H8O)] [IUPAC name: ,L-tetra hydrofuran-2-methanol-O,O')titanium(III)], and (II) [TiCl3(C5H9O2)(C4H 8O)] [IUPAC name: tetrahydrofuran-2-methanolato-O,O')titanium(III)], a re pseudo-octahedral metal complexes of similar structure. The molecul e of tetrahydrofurfuryl alcohol in (I) and its alkoxide anion in (II) act as chelating ligands. Disorder of the two enantiomers of the chela ting ligand occurs in both structures.