2 RUTHENIUM-BLUE PRECURSORS - LORO-HEXAKIS(DIMETHYLPHENYLARSINE)-DIRUTHENIUM(II) TRIFLUOROMETHANESULFONATE AND -MU-BROMO-HEXAKIS(TRIMETHYLARSINE)-DIRUTHENIUM(II) TRIFLUOROMETHANESULFONATE

Authors
HEATH GA HOCKLESS DCR YEOMANS BD
Citation
Ga. Heath et al., 2 RUTHENIUM-BLUE PRECURSORS - LORO-HEXAKIS(DIMETHYLPHENYLARSINE)-DIRUTHENIUM(II) TRIFLUOROMETHANESULFONATE AND -MU-BROMO-HEXAKIS(TRIMETHYLARSINE)-DIRUTHENIUM(II) TRIFLUOROMETHANESULFONATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 854-858
Citations number
14
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
4
Pages
854 - 858
Database
ISI
SICI code
0108-2701(1996)52:<854:2RP-L>2.0.ZU;2-X
Abstract
Confacial bi-octahedral [Ru-2(mu-Cl)(3)(AsMe(2)Ph)(6)]CF3-SO3, (1), an d [Ru-2(mu-Br)(3)(AsMe(3))6]CF3(S)O(3), (2), are the first tertiary-ar sine-capped systems within the wider class of redox-active [L(3)Ru(mu- X)(3)RuL(3)](+/2+) complexes (L = NR(3), PR(3) or AsR(3); X = Cl or Br ) to be structurally characterized. Compounds (1) and (2) have measure d internuclear separations and mean bridgehead angles (Ru-II...Ru-II/R u--X--Ru) of 3.275 (2)/83.5 and 3.413 (1) Angstrom/81.8 degrees, respe ctively.