THYLAMINO)ETHYLIMINOMETHYL]PHENOL)TRIPHENYLTIN(IV) BENZENE HEMISOLVATE, [SNCL(C6H5)(3)(C11H16N2O)].0.5C(6)H(6)

Citation
A. Hazell et al., THYLAMINO)ETHYLIMINOMETHYL]PHENOL)TRIPHENYLTIN(IV) BENZENE HEMISOLVATE, [SNCL(C6H5)(3)(C11H16N2O)].0.5C(6)H(6), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 873-876
Citations number
13
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
4
Pages
873 - 876
Database
ISI
SICI code
0108-2701(1996)52:<873:TBH>2.0.ZU;2-I
Abstract
The coordination geometry of the Sn atom in the title compound is trig onal bipyramidal, with the ipso C atoms of the phenyl groups in equato rial and the Cl and O atoms in apical positions, The ligand is bonded to the Sn atom through the phenolic O atom; the hydroxy H atom is shif ted towards the imino N atom to give rise to a zwitterion, i.e. 2-[2-( dimethylamino)ethyliminiomethyl]-phenolate.