S. Bratovanov et al., ABSOLUTE-CONFIGURATION OF (S)-(-[(BENZYLOXYMETHYL)(TERT-BUTYL)METHYLSILYL] METHYL KETONE()), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1045-1047
The absolute configuration of the title compound was confirmed by an X
-ray crystal structure analysis of (R)-(+)-[(benzyloxymethyl)(tert-but
yl)methylsilyl] methyl ketone 2,4,6-triisopropylphenylsulfonylhydrazon
e, C30H48N2O3SSi, reported herein. The asymmetric unit of the hydrazon
e contains two molecules which are linked by intermolecular hydrogen b
onds.