Ch. Twu et Je. Coon, AN INTERNALLY CONSISTENT APPROACH FOR DETERMINING THE PROPERTIES OF LUMPED COMPONENTS USING A CUBIC EQUATION OF STATE, Fluid phase equilibria, 117(1-2), 1996, pp. 233-240
Cubic equations of state, due to their simplicity and accuracy, are co
mmonly used in reservoir simulation to predict phase behavior of petro
leum reservoir fluids. A cubic equation of state utilizes critical tem
perature, critical pressure, and acentric factor as characterization p
arameters and then tunes the binary interaction parameters between the
components in the mixture to enhance the vapor-liquid equilibrium cal
culations. The results for vapor-liquid equilibrium calculations are s
ensitive to the values of these characterization parameters and binary
interaction parameters in the cubic equation of state. For reservoir
simulation studies, the detailed compositional model is usually replac
ed by a simplified model in which the compositional elements are lumpe
d into a few groups of components rather than many individual componen
ts. This paper presents an internally consistent lumping scheme using
a cubic equation of state for the translation of individual component
critical temperatures, critical pressures, acentric factors, and binar
y interaction parameters between pure components into group critical t
emperature, critical pressure, acentric factor, and binary interaction
parameters between lumped groups. Because the translation procedures
are all internally consistent, the translated characterization paramet
ers used in the cubic equation of state will minimize the loss of info
rmation from the lumping process.