We investigate the NLTE formation of nitrogen lines in Vega and presen
t a new estimate for the nitrogen abundance based on detailed spectrum
synthesis. The NLTE problem is very complex such that our final estim
ate of log epsilon(N) = 7.6 is very uncertain. The statistical equilib
rium of nitrogen is almost completely controlled by the UV flux around
1200 Angstrom, which is sensitive to both the carbon abundance and th
e shape of Lyman alpha. We found that Ly alpha must be included when c
omputing bound-bound rates, a fact not realized before. The sensitivit
y of the NLTE effect to the global metallicity found by Takeda (1992a)
is entirely due to the corresponding change of the carbon abundance.
The inclusion of Ly alpha reduces this sensitivity considerably. Most
accessible N I lines are in the wings of broad Paschen lines which cau
se the NLTE abundance corrections to be different for lines of the sam
e multiplet that occur at different distances from the Paschen line ce
nter. The nitrogen statistical equilibrium is also slightly sensitive
to the collisional excitation cross-sections. For our best estimate, t
he NLTE corrections are considerable, typically Delta[N/H] = -0.4. An
LTE sulphur abundance of log epsilon(S) = 6.93 (or [S/H] = -0.3) has a
lso been determined. Considering all of the available abundances for V
ega, and their likely uncertainties, we find that Vega continues to lo
ok like a mild Lambda Bootis star.