Bs. Yilbas et al., PLASMA NITRIDING OF TI-6AL-4V ALLOY TO IMPROVE SOME TRIBOLOGICAL PROPERTIES, Surface & coatings technology, 80(3), 1996, pp. 287-292
The present study was conducted to investigate the tribological and me
chanical properties of plasma-nitrided Ti-6Al-4V alloy. Specimens were
nitrided in an H-2-N-2 (1:8 ratio) plasma. The nitrogen concentration
along the nitrided zone was obtained using the nuclear reaction analy
sis technique. The workpiece temperature was varied from 450 to 520 de
grees C during the nitriding process. Pin-on-disc wear tests were carr
ied out to evaluate the wear properties of the resultant samples and a
ball-on-disc experiment was conducted to measure the friction coeffic
ient. Microhardness tests, Scanning electron microscopy and X-ray diff
raction were carried out to investigate the phases developed in the ni
trided zone. It was found that the wear resistance improved considerab
ly after the nitriding process. Three distinct layers were identified:
(i) an inner layer where delta-TiN + epsilon-Ti2N phases formed, (ii)
an intermediate layer where alpha-(TiN) with or without epsilon phase
developed and (iii) an outer layer where precipitations were dominant
.