SYNTHESIS AND CHARACTERIZATION OF NEW PHOSPHINE GOLD(I) COMPLEXES - AU[(C6H5)(2)PCH2N(C6H5)(2)]X (X=CL, I) - NMR AND ELECTROCHEMICAL SOLUTION STUDIES

Authors
LARSONNEURGALIBERT AM FABRE PL BRESSON C CASTAN P
Citation
Am. Larsonneurgalibert et al., SYNTHESIS AND CHARACTERIZATION OF NEW PHOSPHINE GOLD(I) COMPLEXES - AU[(C6H5)(2)PCH2N(C6H5)(2)]X (X=CL, I) - NMR AND ELECTROCHEMICAL SOLUTION STUDIES, Journal of chemical research. Synopses, (3), 1996, pp. 168-169
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
3
Year of publication
1996
Pages
168 - 169
Database
ISI
SICI code
0308-2342(1996):3<168:SACONP>2.0.ZU;2-H
Abstract
Reaction of Au(NPm)(2)X (1) with an oxidizing agent such as copper dic hloride or iodine yields Au(NPm)X [NPm = (C6H5)(2)PCH2N(C6H5)(2)]; com pounds 2 (X = Cl) and 3 (X = I) were isolated as microcrystals and cha racterized by elemental analysis, IR, NMR and mass spectroscopy, and t he mechanism of their formation was studied by P-31 NMR and electroche mical techniques.