REGIOSELECTIVITY AND RELATIVE REACTIVITY OF YLIDE FORMATION IN THE REACTION OF KETOCARBENOID WITH HETERO-CUMULENES

Authors
IBATA T HIMORI M FUKUSHIMA K SUGA H NAKANO H
Citation
T. Ibata et al., REGIOSELECTIVITY AND RELATIVE REACTIVITY OF YLIDE FORMATION IN THE REACTION OF KETOCARBENOID WITH HETERO-CUMULENES, Heterocyclic communications, 2(1), 1996, pp. 87-90
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocyclic communications → ACNP
ISSN journal
07930283
Volume
2
Issue
1
Year of publication
1996
Pages
87 - 90
Database
ISI
SICI code
0793-0283(1996)2:1<87:RARROY>2.0.ZU;2-E
Abstract
The regiochemistry of the reaction of ketocarbenoid with phenyl isocya nate, phenyl isothiocyanate, and phenyl isoselenocyanate was studied a nd relative reactivity of these heteromultiple compounds was determine d by competitive reactions. The order of the reactivity and the regio- selectivity in the reactions are explained by molecular orbital calcul ation.