Jp. Lange et Pja. Tijm, PROCESSES FOR CONVERTING METHANE TO LIQUID FUELS - ECONOMIC SCREENINGTHROUGH ENERGY MANAGEMENT, Chemical Engineering Science, 51(10), 1996, pp. 2379-2387
Numerous process schemes have been proposed for converting methane to
liquid hydrocarbon fuels. Economic evaluation studies generally conclu
de that none except the best of these schemes are attractive at presen
t oil prices of <20 $/bb1. Simple arguments are presented here to show
why methane conversion processes are now not economically attractive
and what needs to be done to improve on their economics. Particularly,
an analysis of numerous fuel manufacturing processes based on coal, o
il and gas feedstock will show the need to increase the plant scale, a
nd reduce the energy losses as well as the overall heat and momentum t
ransfer duty. Furthermore, simple calculations of the overall transfer
duty of various methane conversion routes for liquid fuel manufacture
allow us to rank them according to their expected capital cost and id
entify the improvements required for making each route competitive wit
h the cheapest scheme identified here. The conversion routes considere
d here include methane pyrolysis, oxidative coupling, partial oxidatio
n to methanol, methylchloride and methylbisulfate as well as the comme
rcial routes based on synthesis gas.