VAPOR-LIQUID-EQUILIBRIUM DATA OF ALPHA-PINENE PLUS BETA-PINENE PLUS LIMONENE AT 80 KPA AND 101 KPA

Citation
Mf. Rodrigues et Mg. Bernardogil, VAPOR-LIQUID-EQUILIBRIUM DATA OF ALPHA-PINENE PLUS BETA-PINENE PLUS LIMONENE AT 80 KPA AND 101 KPA, Journal of chemical and engineering data, 41(3), 1996, pp. 581-585
Citations number
18
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
00219568
Volume
41
Issue
3
Year of publication
1996
Pages
581 - 585
Database
ISI
SICI code
0021-9568(1996)41:3<581:VDOAPB>2.0.ZU;2-F
Abstract
Vapor-liquid equilibrium data for the ternary system alpha-pinene + be ta-pinene + (S)-(-)-limonene were determined at 80.0 kPa and 101.3 kPa in a modified miniature Othmer still. Parameters of the Wilson, NRTL, and UNIQUAC equations were calculated with the aid of a Nelder-Mead t echnique to minimize an objective function based on the total pressure . Predictions of the ternary data by parameters determined using binar y data were made. The results were compared with the predictions of th e UNIFAC method.