Mf. Rodrigues et Mg. Bernardogil, VAPOR-LIQUID-EQUILIBRIUM DATA OF ALPHA-PINENE PLUS BETA-PINENE PLUS LIMONENE AT 80 KPA AND 101 KPA, Journal of chemical and engineering data, 41(3), 1996, pp. 581-585
Vapor-liquid equilibrium data for the ternary system alpha-pinene + be
ta-pinene + (S)-(-)-limonene were determined at 80.0 kPa and 101.3 kPa
in a modified miniature Othmer still. Parameters of the Wilson, NRTL,
and UNIQUAC equations were calculated with the aid of a Nelder-Mead t
echnique to minimize an objective function based on the total pressure
. Predictions of the ternary data by parameters determined using binar
y data were made. The results were compared with the predictions of th
e UNIFAC method.