VAPOR-LIQUID-EQUILIBRIA OF BINARY-MIXTURES CONTAINING SULFOLANE

Citation
U. Domanska et al., VAPOR-LIQUID-EQUILIBRIA OF BINARY-MIXTURES CONTAINING SULFOLANE, Journal of chemical and engineering data, 41(3), 1996, pp. 624-628
Citations number
26
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
00219568
Volume
41
Issue
3
Year of publication
1996
Pages
624 - 628
Database
ISI
SICI code
0021-9568(1996)41:3<624:VOBCS>2.0.ZU;2-V
Abstract
Isothermal vapor-liquid equilibria at 338.15 K or 353.15 K for sulfola ne + 1-heptyne, + tetrahydrofuran, + 1,4-dioxane, + tetrachloromethane , and + 1,1,1-trichloroethane have been determined using an ebulliomet ric method. The excess molar Gibbs energies determined from the vapor- liquid equilibria are positive for all mixtures, with the maximum vary ing from 480 J . mol(-1) to 1550 J . mol(-1). The results reported are well correlated by the NRTL and UNIQUAC equations.