Rs. Porter et Lh. Wang, ON THE DETERMINATION OF THE MELTING-POINT OF SEMICRYSTALLINE POLYMER BY DSC, Journal of thermal analysis, 46(3-4), 1996, pp. 871-878
This is a study for criteria to judge the melting point of semi-crysta
lline polymers from the DSC endotherm for polymer melting. Beyond stan
dard indium DSC melting results an evaluation has been made on a serie
s of polyethylenes for which crystal sizes were measured and predicted
from Raman LAM analysis. The results confirm the conclusion of Prof.
Wunderlich that the DSC content of melting is the proper basis of repo
rting melting points.