M. Kobayashi et al., SCINTILLATION AND PHOSPHORESCENCE OF PBWO4 CRYSTALS, Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment, 373(3), 1996, pp. 333-346
There are two types of crystals with respect to luminescence. In de me
asurement, type A gives a primary emission at 410-430 nm (blue) with a
second one at around 500 nm. Type B gives only dominant emission at 4
80-500 nm (green). This apparent difference can be interpreted as foll
ows; the characteristic scintillation of PbWO4 is dominantly blue and
subdominantly green. Intense phosphorescence with a decay constant of
about 15 ms exists only in Type B at about 500 nm with one to two orde
rs of magnitude larger intensity than scintillation, hiding the blue s
cintillation in its tail. The cause of the phosphorescence may be Mo.