REACTION OF 2-NITROENAMINES AND 2-NITROALKENYL SULFIDES WITH ETHYL ISOCYANOACETATE - A NOVEL SYNTHESIS OF 1-HYDROXYPYRAZOLES

Authors
UNO H KINOSHITA T MATSUMOTO K MURASHIMA T OGAWA T ONO N
Citation
H. Uno et al., REACTION OF 2-NITROENAMINES AND 2-NITROALKENYL SULFIDES WITH ETHYL ISOCYANOACETATE - A NOVEL SYNTHESIS OF 1-HYDROXYPYRAZOLES, Journal of chemical research. Synopses, (2), 1996, pp. 76
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
2
Year of publication
1996
Database
ISI
SICI code
0308-2342(1996):2<76:RO2A2S>2.0.ZU;2-W
Abstract
The reaction of 2-nitroalkenyl sulfides 2 and 2-nitroenamines 3 with e thyl isocyanoacetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7 -ene gives ethyl 1-hydroxypyrazole-3-carboxylates 4 in moderate to goo d yields.