A. Predoi et al., FAR-INFRARED LASER ASSIGNMENTS AND PREDICTIONS FOR CO-STRETCHING AND CH3-ROCKING STATES OF OPTICALLY PUMPED (CH3OH)-C-13, Infrared physics & technology, 37(3), 1996, pp. 351-366
High-resolution Fourier transform studies of the CO-stretching and CH3
-rocking bands of (CH3OH)-C-13 have been applied to the assignment of
far-infrared (FIR) laser transitions optically pumped by CO2 infrared
(IR) lasers. The assignments are based on spectroscopic identification
of the IR pump transitions at the reported offsets from the CO2 laser
lines and agreement between the FIR laser wavenumbers and values calc
ulated from IR/FIR combination-loop relations. Wavenumbers are also pr
edicted for further potential new FIR laser lines in transition system
s that could be pumped by CO2 and (CO2)-C-13 cw and waveguide lasers.