NEW IMPROVED REAGENTS FOR THE ASYMMETRIC ALLYLATION OF KETONES

Authors
TIETZE LF WEGNER C WULFF C
Citation
Lf. Tietze et al., NEW IMPROVED REAGENTS FOR THE ASYMMETRIC ALLYLATION OF KETONES, Synlett, (5), 1996, pp. 471
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
5
Year of publication
1996
Database
ISI
SICI code
0936-5214(1996):5<471:NIRFTA>2.0.ZU;2-W
Abstract
The synthesis of new 1,2-aminoalcohol derivatives 1b-d and 8a-h and th eir application in the stereoselective allylation of ethyl methyl keto ne is described. The best results were obtained with the biphenyl deri vative 8f, allowing the synthesis of tert-homoallylic ether 9f and 10f with a selectivity of 18:1.