Millimeter-wave observations of the extremely carbon-rich circumstella
r envelope of IRC +10 degrees 216 show several emission lines that we
identify with rotational transitions of methanol. We describe our obse
rvations and the reasoning that led to this identification. We argue t
hat shock chemistry, ion-molecule reactions, and grain surface reactio
ns might all be potential sources of circumstellar methanol. Each of t
hese pathways either requires or produces H2O in the envelope of IRC 10 degrees 216.