RELATION BETWEEN EXCHANGE PROCESS AND STRUCTURE OF AOT REVERSE MICELLAR SYSTEM

Authors
JAIN TK CASSIN G BADIALI JP PILENI MP
Citation
Tk. Jain et al., RELATION BETWEEN EXCHANGE PROCESS AND STRUCTURE OF AOT REVERSE MICELLAR SYSTEM, Langmuir, 12(10), 1996, pp. 2408-2411
Citations number
20
Categorie Soggetti
Chemistry Physical
Journal title
Langmuir → ACNP
ISSN journal
07437463
Volume
12
Issue
10
Year of publication
1996
Pages
2408 - 2411
Database
ISI
SICI code
0743-7463(1996)12:10<2408:RBEPAS>2.0.ZU;2-V
Abstract
The decreases of the exchange micellar rate constant, determined from stopped flow kinetic study, and of the sticky parameter, determined by small angle X-ray scattering, with the water volume fraction are stro ngly correlated. This phenomenon is explained according to the contact value of the micelle-micelle correlation function and the surfactant monolayer rigidity. It is shown that the attractive interactions gover n the decrease of the exchange process with the increase in the number of droplets.