Pk. Bera et al., A COMPARATIVE-STUDY OF 2 EXCIPLEXES - ANTHRACENE-N,N-DIMETHYLANILINE AND ANTHRACENE-JULOLIDINE SYSTEMS, Journal of photochemistry and photobiology. A, Chemistry, 95(2), 1996, pp. 127-136
Two exciplex systems, anthracene-N,N-dimethylaniline and anthracene-ju
lolidine, were studied. Although both N,N-dimethylaniline (DMA) and ju
lolidine are aniline derivatives, they differ with regard to the twist
ing motion of the amino group. A comparative study of the effects of t
he donor concentration, medium polarity, temperature and magnetic fiel
d on the luminescence of the two exciplexes was performed. Differences
in the behaviour of the two exciplexes were ascribed to differences i
n the structures of the two donors.