INFRARED STUDY OF THE INTERACTIONS OF MOISTURE WITH FILTER-PAPER AND THE MOISTURE QUENCHING OF SOLID-MATRIX ROOM-TEMPERATURE PHOSPHORESCENCE

Citation
J. Chen et Rj. Hurtubise, INFRARED STUDY OF THE INTERACTIONS OF MOISTURE WITH FILTER-PAPER AND THE MOISTURE QUENCHING OF SOLID-MATRIX ROOM-TEMPERATURE PHOSPHORESCENCE, Analytica chimica acta, 324(1), 1996, pp. 61-68
Citations number
37
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032670
Volume
324
Issue
1
Year of publication
1996
Pages
61 - 68
Database
ISI
SICI code
0003-2670(1996)324:1<61:ISOTIO>2.0.ZU;2-N
Abstract
Infrared data and solid-matrix room-temperature phosphorescence data w ere correlated with the Young's modulus data of filter paper which con tained various amounts of adsorbed moisture, The results acquired and results from earlier work revealed new insights into the effects of mo isture on the phosphorescence quenching of adsorbed phosphors. The hyd rogen-bonding network in the amorphous region of filter paper was very influential in permitting room-temperature phosphorescence occur, In addition, moisture adsorption resulted in a decrease in the modulus of filter paper which, in turn, had a major affect on the magnitude of i ntensity of solid-matrix phosphorescence. The concept of the filter pa per matrix participating in the quenching of phosphorescence with the adsorption of moisture on paper was considered.