R. Greco et al., POLYETHYLENE POLY(BUTYL METHACRYLATE-CO-STYRENE) COPOLYMERS INTERPENETRATING-LIKE NETWORKS .1. INFLUENCE OF THE COPOLYMER COMPOSITION ON INTERPENETRATING POLYMER NETWORK PROPERTIES/, Journal of macromolecular science. Pure and applied chemistry, A32(12), 1995, pp. 1957-1972
IPN-like systems, consisting of low-density polyethylene (PE) and poly
[butyl methacrylate (BMA)-co-styrene (S)] copolymer networks, were pre
pared in situ by a procedure described in previous papers. The initial
PE/copolymer molar ratio was kept equal to 1 for all samples. The ini
tial molar BMA/S ratio of the copolymer was varied over a composition
range from pure S to pure BMA in order to investigate its influence on
IPN properties. The samples obtained were analyzed by DSC; WAXS; tens
ile mechanical, dynamic-mechanical, and impact tests; swelling in CCI4
; and by some optical and electronic observations. The materials, beca
me more and more brittle after undergoing mechanical and impact tests,
even in the rubbery state, with increasing copolymer BMA content. The
morphology consisted of a two-phase system. Good optical properties w
ere obtained for the transparent specimens at relatively high BMA mola
r contents in the copolymer (70-80% BMA). Reversible changes of the op
tical properties were induced by temperature variations. A matching/mi
smatching of the refractive indexes of PE and the copolymer was found
to be the cause of the optical behavior of these materials. Work is in
progress to improve the mechanical behavior of these systems.