AN UNEXPECTED FORMATION OF DIETHYL TRANS-2,3-PIPERAZINEDICARBOXYLATES

Citation
Ar. Katritzky et al., AN UNEXPECTED FORMATION OF DIETHYL TRANS-2,3-PIPERAZINEDICARBOXYLATES, Heterocyclic communications, 2(2), 1996, pp. 109-113
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
07930283
Volume
2
Issue
2
Year of publication
1996
Pages
109 - 113
Database
ISI
SICI code
0793-0283(1996)2:2<109:AUFODT>2.0.ZU;2-V
Abstract
Heating N-(benzotriazol-1-yl)glycine ethyl esters (2) under bar, obtai ned by Mannich condensation of glycine ethyl esters (1) under bar, for maldehyde and benzotriazole, in THF in the presence of excess of NaH u nexpectedly gave diethyl trans-2,3-piperazinedicatboxylates (3) under bar.