ENERGY-TRANSFER FROM HIGH-DENSITIES OF METASTABLE NF TO IODINE

Authors
Citation
Dj. Benard, ENERGY-TRANSFER FROM HIGH-DENSITIES OF METASTABLE NF TO IODINE, Journal of physical chemistry, 100(20), 1996, pp. 8316-8322
Citations number
27
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
100
Issue
20
Year of publication
1996
Pages
8316 - 8322
Database
ISI
SICI code
0022-3654(1996)100:20<8316:EFHOMN>2.0.ZU;2-T
Abstract
Mixtures of FN3, I-2, HF, and He were shock heated by reflection of an Ma similar to 2 incident wave to generate peak metastable NF concent rations > 10(16)/cm(3). Time profiles of the NF(a), NF(b), I-2, and I concentrations were optically measured and fit to a chemical kinetics and gas dynamic model of the reaction process. Approximately six NF molecules were consumed per I-2 molecule dissociated, and energy trans fer from NF(a) to I was both fast and efficient. Attempts to achieve lasing on the 1315 nm (I --> I) atomic transition were unsuccessful, however, due to rapid E-V quenching of I by the NF species present.