SONOVOLTAMMETRIC MEASUREMENT OF THE RATES OF ELECTRODE PROCESSES WITHFAST COUPLED HOMOGENEOUS KINETICS - MAKING MACROELECTRODES BEHAVE LIKE MICROELECTRODES

Authors
COMPTON RG MARKEN F REBBITT TO
Citation
Rg. Compton et al., SONOVOLTAMMETRIC MEASUREMENT OF THE RATES OF ELECTRODE PROCESSES WITHFAST COUPLED HOMOGENEOUS KINETICS - MAKING MACROELECTRODES BEHAVE LIKE MICROELECTRODES, Chemical communications, (9), 1996, pp. 1017-1018
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1996
Pages
1017 - 1018
Database
ISI
SICI code
1359-7345(1996):9<1017:SMOTRO>2.0.ZU;2-G
Abstract
Voltammetric measurements of the rates of fast homogeneous chemical re actions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ort ho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power u ltrasound to confer fast mass-transport properties so giving the elect rodes the kinetic timescale of microelectrodes.