CONFORMATIONAL EFFECTS ON STEREOSELECTIVITIES IN ELECTRON-TRANSFER AND ION-ASSOCIATION REACTIONS BETWEEN METAL-COMPLEXES

Authors
TATEHATA A MITANI T
Citation
A. Tatehata et T. Mitani, CONFORMATIONAL EFFECTS ON STEREOSELECTIVITIES IN ELECTRON-TRANSFER AND ION-ASSOCIATION REACTIONS BETWEEN METAL-COMPLEXES, Chemical communications, (9), 1996, pp. 1033-1034
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1996
Pages
1033 - 1034
Database
ISI
SICI code
1359-7345(1996):9<1033:CEOSIE>2.0.ZU;2-M
Abstract
The stereoselectivities in the oxidation of [Co(pn)(3)](2+) (pn = 1,2- propanediamine) by Delta-[Co(glyO)(ox)(2)](2)(glyO = glycinate, ox = o xalate) and in ion-association of (lel)(3)- and (ob)(3)-[Co(pn)(3)](3) with the same anionic complex are observed to be dependent on the ch elate-ring conformation and are indications of the importance of the e lectron-transfer step within a precursor assembly in the overall elect ron-transfer stereoselectivity.