ATYPICAL CARBON-CARBON BOND SCISSION AND DEOXYGENATION IN THE PROTONATION OF TUNGSTEN-ETA(1)-OXABICYCLIC COMPOUNDS

Authors
SHIU LH SHU HK CHENG DH WANG SL LIU RS
Citation
Lh. Shiu et al., ATYPICAL CARBON-CARBON BOND SCISSION AND DEOXYGENATION IN THE PROTONATION OF TUNGSTEN-ETA(1)-OXABICYCLIC COMPOUNDS, Chemical communications, (9), 1996, pp. 1041-1042
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
9
Year of publication
1996
Pages
1041 - 1042
Database
ISI
SICI code
1359-7345(1996):9<1041:ACBSAD>2.0.ZU;2-G
Abstract
Treatment of tungsten-eta(1)-7-oxabicyclo[2.2.1]heptadiene and -eta(1) -7-oxabicyclo[2.2.1]heptene with CF3SO3H leads to atypical carbon-carb on bond scission and deoxygenation; the reaction intermediates in the bond scission involves a tungsten-eta(1)-2-hydrofurylium cation.