Translucent ZrO2 film was successfully prepared by gelling hydrotherma
lly produced nano-ZrO2 powders. The film (300 mu m thick) was found to
transmit light to 6.5 mu m (40% transmission) when sintered at 1200 d
egrees C, but transmission was totally lost after sintering at 1300 de
grees C for 1 h. Residual organic material such as urea, which was use
d for preparing the powder, dominated the transmission of the film in
the region between 1.3 and 4.5 mu m when sintered below 1000 degrees C
. When sintered above 1000 degrees C, the microstructure controlled th
e transmission. Both organic residuals and the microstructure of the z
irconia were found to determine the transmission in 4.5-6.5 mu m regio
n.