PD(II) INHIBITION DURING HEXACYANOFERRATE(III) OXIDATION OF SUGARS - A KINETIC-STUDY

Authors
BAJPAI P SHUKLA A UPADHYAY SK
Citation
P. Bajpai et al., PD(II) INHIBITION DURING HEXACYANOFERRATE(III) OXIDATION OF SUGARS - A KINETIC-STUDY, International journal of chemical kinetics, 28(6), 1996, pp. 413-419
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
28
Issue
6
Year of publication
1996
Pages
413 - 419
Database
ISI
SICI code
0538-8066(1996)28:6<413:PIDHOO>2.0.ZU;2-L
Abstract
An inhibition effect of PdCl2 on the rate of oxidation of sugars, by a lkaline hexacyanoferrate(III) has been observed. The order of reaction s in hexacyanoferrate(III) and OH- is zero and unity, respectively, wh ile that in sugars decreases From unity al higher sugar concentration. The kinetic data and spectrophotometric evidence support the formatio n of {Pd-II - (sugar)} and {Pd-II - sugar)(2)} complexes and their res istance to react with Fe(CN)(6)(3-). (C) 1996 John Wiley & Sons, Inc.