ALLYL 1,1-BIMETALLIC SPECIES - THEIR PREPARATION AND REACTIVITY PROFILE

Authors
LAUTENS M BEN RN DELANGHE PHM
Citation
M. Lautens et al., ALLYL 1,1-BIMETALLIC SPECIES - THEIR PREPARATION AND REACTIVITY PROFILE, Tetrahedron, 52(21), 1996, pp. 7221-7234
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
21
Year of publication
1996
Pages
7221 - 7234
Database
ISI
SICI code
0040-4020(1996)52:21<7221:A1S-TP>2.0.ZU;2-E
Abstract
A synthesis of novel allyl 1,1-hetero- and homobimetallic compounds wh ere M=Sn or Si' and M'=Si via a palladium catalyzed reduction employin g ammonium formate is described. The regioselectivity in the reduction s is routinely >99:1. Reaction of these novel reagents was also invest igated with various electrophiles and compared to the well studied cro tyl- and allylstannane and silanes. Copyright (C) 1996 Elsevier Scienc e Ltd