DIASTEREOSELECTIVE SYNTHESIS OF HETEROSUBSTITUTED ORGANOGEMBISMETALLIC REAGENTS - APPLICATION TO A NEW PROPARGYLMETALATION REACTION OF VINYL METALS

Authors
BRASSEUR D MAREK I NORMANT JF
Citation
D. Brasseur et al., DIASTEREOSELECTIVE SYNTHESIS OF HETEROSUBSTITUTED ORGANOGEMBISMETALLIC REAGENTS - APPLICATION TO A NEW PROPARGYLMETALATION REACTION OF VINYL METALS, Tetrahedron, 52(21), 1996, pp. 7235-7250
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
21
Year of publication
1996
Pages
7235 - 7250
Database
ISI
SICI code
0040-4020(1996)52:21<7235:DSOHO>2.0.ZU;2-J
Abstract
The allylzincation and propargylzincation of various gamma-heterosubst ituted vinyl metals proceed diastereoselectively. This represents a ne w synthetic approach to construct two or three adjacent stereogenic ce nters in acyclic systems. Copyright (C) 1996 Elsevier Science Ltd