RING-CLOSING OLEFIN METATHESIS FOR THE SYNTHESIS OF FUSED NITROGEN-HETEROCYCLES

Citation
Sf. Martin et al., RING-CLOSING OLEFIN METATHESIS FOR THE SYNTHESIS OF FUSED NITROGEN-HETEROCYCLES, Tetrahedron, 52(21), 1996, pp. 7251-7264
Citations number
61
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
52
Issue
21
Year of publication
1996
Pages
7251 - 7264
Database
ISI
SICI code
0040-4020(1996)52:21<7251:ROMFTS>2.0.ZU;2-G
Abstract
A novel technique for the efficient synthesis of fused nitrogen hetero cycles containing various combinations of five- and eight-membered rin gs has been developed. This method features the ring-closing metathesi s (RCM), which is catalyzed by the molybdenum alkylidene complex 6, of alpha,omega-dienes that have a nitrogen atom in the chain linking the two olefinic functional groups. Copyright (C) 1996 Elsevier Science L td