STEREOSELECTIVE SYNTHESES OF 1,2-DIALKYL-1-PHENYL CYCLOPENTANES INVOLVING INTRAMOLECULAR CARBOLITHIATION OF OLEFINS

Authors
KRIEF A KENDA B MAERTENS C REMACLE B
Citation
A. Krief et al., STEREOSELECTIVE SYNTHESES OF 1,2-DIALKYL-1-PHENYL CYCLOPENTANES INVOLVING INTRAMOLECULAR CARBOLITHIATION OF OLEFINS, Tetrahedron, 52(21), 1996, pp. 7465-7473
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
21
Year of publication
1996
Pages
7465 - 7473
Database
ISI
SICI code
0040-4020(1996)52:21<7465:SSO1CI>2.0.ZU;2-7
Abstract
2-Ethyl-1-methyl-1-phenyl cyclopentane, unavailable by butyllithium-pr omoted carbocyclisation of the corresponding alkenyl selenide, has bee n efficiently produced using two different strategies involving the ca rbocyclisation of 6-phenyl-6-methylseleno-1-heptene as the key step. C opyright (C) 1996 Elsevier Science Ltd