BIOMIMETIC SYNTHESIS OF THE MICROBIAL ELICITOR SYRINGOLIDE-2

Authors
HENSCHKE JP RICKARDS RW
Citation
Jp. Henschke et Rw. Rickards, BIOMIMETIC SYNTHESIS OF THE MICROBIAL ELICITOR SYRINGOLIDE-2, Tetrahedron letters, 37(20), 1996, pp. 3557-3560
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
20
Year of publication
1996
Pages
3557 - 3560
Database
ISI
SICI code
0040-4039(1996)37:20<3557:BSOTME>2.0.ZU;2-K
Abstract
Syringolide 2 (1; n=2), an elicitor metabolite of the bacterial plant pathogen Pseudomonas syringae pv. tomato, has been synthesised in four steps from D-xylulose. The key stage involves triple cyclisation of t he putative biosynthetic intermediate 1-(3'-oxodecanoyl)-D-xylulose (9 ), and provides evidence for the biosynthesis of the syringolides. Cop yright (C) 1996 Published by Elsevier Science Ltd