Citation
H. Barlage et H. Jacobs, NA4BR(NH2)(3) - AN AMIDE BROMIDE IN THE S YSTEM NANH2 NABR/, Zeitschrift fur anorganische und allgemeine Chemie, 622(5), 1996, pp. 895-897
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313
→ ACNP
Volume
622
Issue
5
Year of publication
1996
Pages
895 - 897
Database
ISI
SICI code
0044-2313(1996)622:5<895:N-AABI>2.0.ZU;2-N
Abstract
The pseudobinary system NaNH2/NaBr was investigated by X-ray methods.
The crystal structure of Na4Br(NH2)(3) was solved by single crystal da
ta: Pnnm, Z = 4, a = 6.579(2) Angstrom, b = 12.755(4) Angstrom, c = 8.
776(2) Angstrom Z(F-o) with (F-o)(2) greater than or equal to 3 sigma
= (F-o)(2) = 503, Z(parameter) = 39, R/R(w) = 0.082/0.106. It is a new
type of structure, built up by a three-dimensional network of (3)(inf
inity)[Na-4(NH2)(3)(+)] containing the bromide ions.