RING-OPENING REACTIONS OF TI-DODECAISOPROPYLTRICYCLO[4.2.0.0(2,5)]OCTASILANE - FORMATION OF NOVEL BICYCLO[3.3.0]OCTASILANE AND BICYCLO[4.2.0]OCTASILANE SYSTEMS

Authors
KYUSHIN S SAKURAI H YAMAGUCHI H MATSUMOTO H
Citation
S. Kyushin et al., RING-OPENING REACTIONS OF TI-DODECAISOPROPYLTRICYCLO[4.2.0.0(2,5)]OCTASILANE - FORMATION OF NOVEL BICYCLO[3.3.0]OCTASILANE AND BICYCLO[4.2.0]OCTASILANE SYSTEMS, Chemistry Letters, (5), 1996, pp. 331-332
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
5
Year of publication
1996
Pages
331 - 332
Database
ISI
SICI code
0366-7022(1996):5<331:RROT>2.0.ZU;2-7
Abstract
The reaction of anti-dodecaisopropyltricyclo[4.2.0.0(2.5)] silane (1) with PdCl2(PhCN)(2) gave bicyclo[3.3.0]octasilane (trans-2) and bicycl o[4.2.0]octasilane (trans-3). In the reaction of 1 with PCl5, only the bicyclo[4.2.0]octasilanes (cis-3 and trans-3) were formed. The struct ures of the novel rings, trans-2, cis-3, and trans-3, were investigate d by X-ray crystallography.